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Related to Rearrangement reaction: addition reaction, Beckmann rearrangement, Pericyclic reaction
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Substituent groups at 2-position of 5-methyl-3-nitrosoindolizine derivatives are critical for the rearrangement reaction and have slight effect on the denitrosylation.
In order to prepare this unique material, the UBC group took advantage of a [1,3]-silatropic rearrangement reaction (eq.
To this end, I propose the innovative harvesting of the potential of vinyl cation intermediates as platforms for the deployment of nucleophilic entities capable of orchestrating rearrangement reactions. The combination of such high-energy intermediates, generated under mild conditions, with the power of carefully designed rearrangements leads to an array of useful new transformations.